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Looks like your email is invalid. Update email. Would you like to receive Drama. Fever news and exclusive promotions? Would you like to receive Drama. Fever news and exclusive promotions? Would you like to receive Drama. Fever promotions? Yes, subscribe me. Please disable compatibility mode to improve your experience. Our website may look like a mismatched Mr. Potato Head with it turned on. Click here to learn how. It looks like you don't have Adobe Flash Player installed. Without it, your Drama. Fever experience will be like watching TV with blindfolds on. Click here to download and install. Your browser is on the brink of extinction. Try one of these awesome modern browsers to fully take advantage of all that Drama. Fever has to offer! Click here to download and install. Romance of Three Kingdoms - Part I(. Thanks for your understanding. Romance of the Three Kingdoms XIII (Sangokushi 13Romance of the Three Kingdoms XI Download Features. Vivid 3D scenes inspired by classical Chinese ink paintings. Domestic affairs, diplomacy and warfare are seamlessly integrated and conducted on a vast 3D map of China. Romance of the Three Kingdoms XI Review. Hitman Episode 4: Bangkok Review. Metroid Prime: Federation. The official site of Romance of the Three Kingdoms 11 for PC. It took four years and 1. Chinese dramas to be produced. Because of the length and scope of the drama, some actors took up several roles, and some roles had more than one actor portraying it. In Part 1, The Heroes Struggle for Power, we are first introduced to the three great military generals of China, during that period - Liu Bei, Guan Yu, and Zhang Fei. Beginning with the Oath of the Peach Garden, where these three generals swear brotherhood to one another, the first part takes us through all the wars as three men vie for power in China. It ends with the game- changing Battle of Guandu.
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The program draws young people, generally (but not exclusively) under the age of. ANZ Summer Intern Program. Country selector, press enter to show hide list. Selected country is Australia. Be BOLD—Explore the internship designed to create impact and build leaders. Read more See the scholarships and grants Google offers Read more Google in Residence. Login here Contact Information Administration & Human Resource Development Directorate, AU Commission P.O. Box 3243 Addis Ababa, Ethiopia. Fax: 00251-11-5525840 00251-11-5510430 [email protected]. The Navitas Professional Internship Program offers internships in Australia. The work internship provides participants with the opportunity for personal and professional growth. Basic Concepts in Electrochemistry. 2 Electrochemical Cell Electrons Current + -. Electrolysis Cell Electrons (2 e) Current + - ANODE CATHODE Current Voltage Source. Notes on electrolysis of substances. Books Audiobooks Comics Sheet Music. Hand-picked favorites from our editors. Electro-Chemical reaction Engineering Electrode Reactions. Electrolysis - Wikipedia, the free encyclopedia. This article is about the chemical process. A summary of Electrolysis in 's Electrolytic Cells. Learn exactly what happened in this chapter, scene, or section of Electrolytic Cells and what it means. Chemistry 12 Notes on Unit 5-Redox Electrolytic Cells Chemistry 12—Notes on Electrolytic Cells Page 41 Electrolytic Cells (ELC’s) Electrolysis – uses an. Electrolysis is the break-up of a chemical compound using an electric current. See similar resources. For the cosmetic hair removal procedure, see Electrology. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. History. Choice of suitable electrode depends on chemical reactivity between the electrode and electrolyte and manufacturing cost. Process of electrolysis. The desired products of electrolysis are often in a different physical state from the electrolyte and can be removed by some physical processes. For example, in the electrolysis of brine to produce hydrogen and chlorine, the products are gaseous. These gaseous products bubble from the electrolyte and are collected. Positively charged ions (cations) move towards the electron- providing (negative) cathode. Negatively charged ions (anions) move towards the electron- extracting (positive) anode. In this process electrons are either absorbed or released. Neutral atoms gain or lose electrons and become charged ions that then pass into the electrolyte. The formation of uncharged atoms from ions is called discharging. When an ion gains or loses enough electrons to become uncharged (neutral) atoms, the newly formed atoms separate from the electrolyte. Positive metal ions like Cu++ deposit onto the cathode in a layer. The terms for this are electroplating, electrowinning, and electrorefining. When an ion gains or loses electrons without becoming neutral, its electronic charge is altered in the process. In chemistry, the loss of electrons is called oxidation, while electron gain is called reduction. Oxidation and reduction at the electrodes. For example, it is possible to oxidize ferrous ions to ferric ions at the anode: Fe. For example: p- Benzoquinone can be reduced to hydroquinone at the cathode: + 2 e. Electrolysis reactions involving H+ ions are fairly common in acidic solutions. In aqueous alkaline solutions, reactions involving OH. It is even possible to have electrolysis involving gases. Such as when using a Gas diffusion electrode. Energy changes during electrolysis. The losses can (in theory) be arbitrarily close to zero, so the maximum thermodynamic efficiency equals the enthalpy change divided by the free energy change of the reaction. In most cases, the electric input is larger than the enthalpy change of the reaction, so some energy is released in the form of heat. In some cases, for instance, in the electrolysis of steam into hydrogen and oxygen at high temperature, the opposite is true and heat energy is absorbed. This heat is absorbed from the surroundings, and the heating value of the produced hydrogen is higher than the electric input. Related techniques. Though related via the interaction of ions and electrodes, electrolysis and the operation of electrochemical cells are quite distinct. A chemical cell should not be thought of as performing electrolysis in reverse. Faraday's laws of electrolysis. This became the basis of the first law of electrolysis: m=k. Electroplating is used in many industries for functional or decorative purposes, as in vehicle bodies and nickel coins. Production of hydrogen for fuel, using a cheap source of electrical energy. Electrolytic etching of metal surfaces like tools or knives with a permanent mark or logo. Electrolysis is also used in the cleaning and preservation of old artifacts. Because the process separates the non- metallic particles from the metallic ones, it is very useful for cleaning a wide variety of metallic objects, from old coins to even larger objects including rustedcast ironcylinder blocks and heads when rebuilding automobile engines. Rust removal from small iron or steel objects by electrolysis can be done in a home workshop using simple materials such as a plastic bucket, tap water, lengths of rebar, washing soda, baling wire, and a battery charger. However, with salts of some metals (e. In both cases this is due to water being reduced to form hydrogen or oxidized to form oxygen. In principle the voltage required to electrolyze a salt solution can be derived from the standard electrode potential for the reactions at the anode and cathode. The standard electrode potential is directly related to the Gibbs free energy, . An extract from the table of standard electrode potentials is shown below. Half- reaction. E. For example, it is more difficult to reduce a sodium ion to a sodium metal than it is to reduce a zinc ion to a zinc metal. Reduced species (often an anion) with a more positive cell potential are more difficult to oxidize than reduced species with a more negative cell potential. For example, it is more difficult to oxidize sulfate anions than it is to oxidize bromide anions. Using the Nernst equation the electrode potential can be calculated for a specific concentration of ions, temperature and the number of electrons involved. For pure water (p. H 7): the electrode potential for the reduction producing hydrogen is . The conclusion from these figures is that hydrogen should be produced at the cathode and oxygen at the anode from the electrolysis of water. In practice many other factors have to be taken into account such as the kinetics of some of the reaction steps involved. These factors together mean that a higher potential is required for the reduction and oxidation of water than predicted, and these are termed overpotentials. Experimentally it is known that overpotentials depend on the design of the cell and the nature of the electrodes. For the electrolysis of a neutral (p. H 7) sodium chloride solution, the reduction of sodium ion is thermodynamically very difficult and water is reduced evolving hydrogen leaving hydroxide ions in solution. At the anode the oxidation of chlorine is observed rather than the oxidation of water since the overpotential for the oxidation of chloride to chlorine is lower than the overpotential for the oxidation of water to oxygen. The hydroxide ions and dissolved chlorine gas react further to form hypochlorous acid. The aqueous solutions resulting from this process is called electrolyzed water and is used as a disinfectant and cleaning agent. Research trends. The efficiency of an electrolyser is a measure of the enthalpy contained in the hydrogen (to undergo combustion with oxygen, or some other later reaction), compared with the input electrical energy. Heat/enthalpy values for hydrogen are well published in science and engineering texts, as 1. MJ/kg. Note that fuel cells (not electrolysers) cannot utilise this full amount of heat/enthalpy, which has led to some confusion when calculating efficiency values for both types of technology. In the reaction, some energy is lost as heat. Some reports quote efficiencies between 5. PEM (Polymer Electrolyte Membrane electrolysis) and catalytic technology, such as 9. Hydrogen is used for the creation of ammonia for fertilizer via the Haber process, and converting heavy petroleum sources to lighter fractions via hydrocracking. Electrocrystallization. The technique has been used to obtain single crystals of low- dimensional electrical conductors, such as charge- transfer salts. The Chemical news and journal of industrial science; with which is incorporated the . Retrieved 2. 7 February 2. Understanding solids: the science of materials. ISBN 9. 78- 0- 4. Retrieved 2. 2 October 2. Retrieved April 1, 2. Physical Chemistry, 6th edition (W. H. Freeman and Company, New York).^ abc. Van. Vogel, 1. 95. A textbook of Quantitative Inorganic Analysis, Longmans, Green and Co^Y. Hori, in Modern Aspects of Electrochemisty , ed. Gamboa- Aldeco, Springer, New York, 2. Qiao, et al., A review of catalysts for the electroreduction of carbon dioxide to produce low- carbon fuels, Chem. Soc. Rev., 2. 01. Carmo, M; Fritz D; Mergel J; Stolten D (2. Journal of Hydrogen Energy. Part 4: Production from electricity by means of electrolysis. Sverdrup (March 2. National Renewable Energy Laboratory. Retrieved 2. 0 October 2. Synthesis, structure, and conductivity of bis(tetramethyltetraselenafulvalenium) perchlorate, (TMTSF)2. Cl. O4. Journal of the American Chemical Society. IB Chemistry higher level notes: Electrolysis. Solutions in water contain hydrogen. These H+ and. OH- ions compete at the electrodes with the solute ions. The ions that are successfully released at the electrodes depend on three. The position of the ion in the electrochemical series. The concentration of the ion in the solution. The nature of the electrode. The position of the ion in the electrochemical series. This is probably better expressed as the position of the redox equilibrium. All the redox equilibria are expressed. Cu. 2+ + 2e. Cu However, going from the right hand side to the left hand. Hence it may be called a redox equilibrium. This is more positive than hydrogens electrode potential of. V. This means that copper ions are more easily reduced (i. Consequently in a competition between the two ions the copper. As a rule of thumb, if the metal appears below hydrogen. The concentration of the ions. When two ions with similar reactivity are in competition. The nature of the electrode. Usually, inert electrodes such as graphite or platinum are used for electrolysis. However, if metal electrodes are used in metal ion solutions they can. Example: Electrolysis of sodium chloride. The ions present in the solution are. Na+. . Cl- . . H+. OH- . At the cathode. The positive ions are attracted to the negative cathode. There. is competition between the sodium ions and the hydrogen ions. As. the hydrogen ion . The chloride ions compete with the hydroxide. Whe the solution is. Cl- - 2e. Cl. 2Ions remaining in solution. The ions that are removed from the solution, then. This means that the. Note: When the solution of chloride ions is dilute. OH. There. is competition between the copper ions and the hydrogen ions. As. the hydrogen ion . The sulphate ions compete with the hydroxide. The hydroxide ions. AS OXYGEN GAS and water. OH- - 4e. 2. H2. O + O2. Ions remaining in solution. The ions that are removed from the solution, then. This means that the. Example: Electrolysis of copper(II) sulphate. The ions present in the solution are. Cu. 2+. SO4. 2- . H+. . OH- . At the cathode. The positive ions are attracted to the negative cathode. There. is competition between the copper ions and the hydrogen ions. As. the hydrogen ion . Cu - 2e. Cu. 2+Ions remaining in solution. Copper is deposited at the cathode and is dissolved. Consequently the concentration of copper ions in solution. This can be used as a method of purification of. In this purification an anode made of impure copper. Summary. Reactive metals (more reactive than hydrogen) are never deposited during. If the metal ion comes from a metal. Halide ions (chloride, bromide, iodide) are released preferentially and. Unreactive metals, such as copper or nickel, may participate in reactions. List the factors affecting the amount of product. Factors are charge on the ion, current and. Products of electrolysis. The ions involved in elecrolysis are picking up electrons and depositing. It is apparent that the number of ions involved. It will also depend on the charges of the ions involved. Relationship between current and number of electrons. Each electron posseses an electrical charge and the movement of the electrons. Q'. This is related to the electrical current as follows: 1 Ampere of current (I) is the passage of 1 Coulomb (C) of charge per. To calculate the number of coulombs of charge it is necessary to multiply. One mole of electrons has a charge equivalent to 9. Faraday of charge (F)Charge on the ion. So, to release one mole of a singly charged ion at an electrode exactly. Faraday of charge (9. C) must pass through the electrode. If the ion has a double charge then two moles of electrons (2 Faradays). Example Calculate the number of moles of hydrogen. Then: -Q = 5 x 3. C Therefore: -Q = 1. Faradays In the electrolysis the hydrogen gas is released at the cathode. H+ + 2e. H2. 2 moles of electrons release 1 mole of gas. Faradays of charge are needed to release 1 mole of hydrogen. Therefore 0. 1. 55 F releases 0. Therefore moles of hydrogen released = 0. Example Calculate the number of coulombs needed to. No of moles Cu =. In electrolysis copper metal is released at the cathode as follows: Cu. Cu 2 moles of electrons release 1 mole of copper. Therefore 0. 2 moles of electrons release 0. Faradays = 0. 2 x 9. Calculate the time that a current of 4 amps. Q = It. 19,3. 00 coulombs = It. Therefore t = 1. 9,3. Determine the relative amount of products formed. Relative quantities of product. As ions have different charges it follows that diffierent ions will require. For example, copper ions have a 2+ charge, whereas silver ions have a. It follows, then, that twice as many electrons are. Therefore for the same number of moles of electrons - i. Example. In the following diagram the number of moles of silver deposited will. The number of moles. Useful links. Electrolysis. Purdue Universityhttp: //members. Electrolysis. Industrial. Freeware vs Shareware - Difference and Comparison History In 1. Andrew Fluegelman created a telecommunications program for IBM PC and named it PC- Talk. He used the term freeware for PC- Talk and that was how this word was coined. Within a few months of this, Bob Wallace developed a word processor, PC- Write and called it shareware. But Andrew Fluegelman initially did not distribute the software freely, thus making it a shareware. The authors or developers of freeware and shareware are programmers and their programs are of comparable quality. 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In practice and in its aims it is often closely related to systems engineering, industrial engineering, change management, and business transformation. The program manager has oversight of the purpose and status of the projects in a program and can use this oversight to support project- level activity to ensure the program goals are met by providing a decision- making capacity that cannot be achieved at project level or by providing the project manager with a program perspective when required, or as a sounding board for ideas and approaches to solving project issues that have program impacts. In a program there is a need to identify and manage cross- project dependencies and often the project management office (PMO) may not have sufficient insight of the risk, issues, requirements, design or solution to be able to usefully manage these. The program manager may be well placed to provide this insight by actively seeking out such information from the project managers although in large and/or complex projects, a specific role may be required. However this insight arises, the program manager needs this in order to be comfortable that the overall program goals are achievable. Overview and definition. Acquisition Specialist Job Description by William Henderson. An acquisition specialist’s responsibilities vary. What Is the Job Description for a Program Specialist for Autistic Behavior? Only when that capability is transferred to the line management and utilized by the host organization will the benefits actually be delivered. On this view, a program team cannot, on their own, deliver benefits. Benefits can only be delivered through the utilization of a new capability. Programs are normally designed to deliver the organisation's strategy or business transformation, such as an ambition to be the fourth biggest supermarket in a region by 2. According to one source, . Programs may include elements of related work outside of the scope of the discrete projects in the program.. Some projects within a program can deliver useful incremental benefits to the organization before the program itself has completed. Program managers should not micromanage, but should leave project management to the project managers. However, program management might need to deal with interdependencies, conflicts and resource or knowledge sharing among the projects it manages. In public sector work in Europe, the term normally refers to multiple change projects: projects that are designed to deliver benefits to the host organization. For example, the Office of Government Commerce for the UK government. An alternative to the Office of Government Commerce's methodology for program management is that of the private sector Project Management Institute. Many organizations only run one program at a time, a program containing all their projects. In Project Management Institute terminology, this is more likely to be a project portfolio than a program. Some larger organizations may have multiple programs each designed to deliver a range of improvements. Some organizations use the concept of Systems Engineering where others use program management. Key factors. Governance must include a set of metrics to indicate the health and progress of the program in the most vital areas. Alignment. The program must support a higher level vision, goals and objectives. This is an example of Acquisition Program Manager resume with objective, responsibilities and experience that will guide you to write an optimized resume for your job application. It’s a broad set of responsibilities that cover more internal policy and external communications than individual corporate. Typical Duties of a Talent Acquisition Manager. Elite Partner Program; Contributors; Terms. Assurance. Verify and validate the program, ensuring adherence to standards and alignment with the vision. Management. Ensure there are regular reviews, there is accountability, and that management of projects, stakeholders and suppliers is in place. Integration. Ensure that component parts fit together properly to make the intended whole. Optimize performance across the program value chain, functionally and technically. Finances. Track basic costs together with wider costs of administering the program. Infrastructure. Allocation of resources influences the cost and success of the program. Infrastructure might cover offices, version control, and IT. Planning. Develop the plan bringing together the information on projects, resources, timescales, monitoring and control. On one view, projects deliver outputs, discrete parcels or . By combining these projects with other deliverables and changes, their programs might deliver increased income from a new product, shorter waiting lists at the hospital or reduced operating costs due to improved technology. On this second view, the point of having a program is to exploit economies of scale and to reduce coordination costs and risks. The project manager's job is to ensure that their project succeeds. The program manager, on the other hand, is concerned with the aggregate outcome(s) or end- state result(s) of the collection of projects in a particular program. For example, in a financial institution a program may include one project that is designed to take advantage of a rising market and another that is designed to protect against the downside of a falling market. The former seeks to leverage the potential upside; the latter to limit the possible downside. Consider a simple analogy: Fix- A- Flat. This highly- pressurized aerosol product injects a leak sealant into a punctured tire to stop the outflow of air (project A) and concurrently re- inflates the tire (project B), resulting together in the outcome that is a tire that is once again functional (the program comprised projects A and B). The program manager has been described as 'playing chess' and keeping the overview in mind, with the pieces to be used or sacrificed being the projects. And also according to this view, successful projects deliver on time, to budget and to specification, whereas successful programs deliver long term improvements to an organization. Improvements are usually identified through benefits. An organization should select the group of programs that most take it towards its strategic aims while remaining within its capacity to deliver the changes. On the other hand, the view that programs are simply large projects or a set of projects allows that a program may need to deliver tangible benefits quickly. According to one source, the key difference between a program and a project is the finite nature of a project. A program is ongoing and implemented within a business to consistently achieve certain results for the business. A project is designed to deliver an output or deliverable and its success will be in terms of delivering the right output at the right time and to the right cost. Program management includes management of projects which, together, improve the performance of the organization. A program's success will be measured in terms of benefits. Benefits are the measures of improvement of an organization and might include increased income, increased profits, decreased costs, improved market position (ability to compete), reduced wastage or environmental damage, more satisfied customers. In central or local government organizations, benefits might include providing a better service to the community. In the course of achieving required results, business programs will normally understand related business constraints and determine the processes required to achieve results based on resources allocated. Improvement of processes is a continuous operation that very much contrasts a program from a project. At the lowest level project managers co- ordinate individual projects. They are overseen by the program manager who accounts to the program sponsor (or board). There will normally be a process to change the predetermined scope of a project. Programs often have to react to changes in strategy and changes in the environment in which the organization changes. Another view and another successful way of managing does not see any of the factors listed above as distinguishing projects from programs, but rather sees the program as being about portfolio management. On this view, program management is about selecting projects, adjusting the speed at which they run, and adjusting their scope, in order to the maximize the value of the portfolio as a whole, and as economic or other external conditions change. Yet another view is that a program management is nothing more than a large, complex project, where the integration aspect of project management is more important than in smaller projects. Integration management is a key feature of the Project Management Institute's approach to project management. In practice it is not clear that there is such a clear- cut distinction. 18,347 Acquisition Program Manager Jobs available on Indeed.com. Apply to 3,467 Acquisition Program Manager jobs in United States on LinkedIn. Sign-up today, leverage your professional network, and get hired. New Acquisition Program Manager jobs added daily. The Acquisition Manager is responsible for helping a department or company increase sales for both short term and long term. He/she works to increase a com. Chapter 4 Responsibilities and Authorities. Approves selections for Program Executive Officer (PEO), Direct Reporting Program Manager (DRPM), and Acquisition Category (ACAT) I/II PM positions. The ASN(RDA), via the. Projects (or programs) vary from small and simple to large and complex; what needs to be a managed as a program in one culture or organization may be managed as a project in another. Acquisition Program Manager, Senior at Tetra Tech. As a leading provider of consulting, engineering, and technical services worldwide, Tetra Tech seeks clear sustainable solutions that improve the quality of life. To achieve and sustain our goals, we need your talent and energy! As a member of our team, you will be encouraged to think outside the box and explore new technologies, ideas, and business trends that contribute to your personal and professional development as well as company success. A career with Tetra Tech means a diverse, collaborative work environment, opportunities to involve yourself in self- directed project efforts, work/life balance, and a wide range of benefits. With offices and project opportunities in locations around the world, you can find an opportunity that matches your career goals and geographic preference. Come discover how rewarding a career with Tetra Tech can be. Join the Tetra Tech Talent Network today and check out our current opportunities! What is a Talent Network? Talent Networks enhance your job search and application process. Whether you choose to apply or just leave your information, we look forward to staying connected with you. Why Join? Receive alerts with new job opportunities that match your interests. Share job opportunities through Social Media or email. |
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January 2017
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